Tris(triphenylphosphine)nickel CAS 25136-46-3
| CAS No. | 25136-46-3 |
| Molecular Formula | C54H45NiP3 |
| Molecular Weight | 845.55 g/mol |
| Category | Pharmaceutical Standards / API Standards |
| Availability | In Stock |
Chemical Structure
Description
The occurrence of Tris(triphenylphosphine)nickel is closely related to organophosphorus functionality, a polycyclic aromatic system in its molecular formula, which determines its behaviour during synthesis, purification, or degradation.
Tris(triphenylphosphine)nickel (CAS 25136-46-3), molecular formula C54H45NiP3 and molecular weight 845.55 g/mol, is a CATO reference standard with documented purity and traceability.
Owing to organophosphorus functionality, a polycyclic aromatic system, Tris(triphenylphosphine)nickel is typically pale yellow to yellow amorphous powder. Its solid-state physicochemical attributes — including a molecular weight of 845.55 g/mol — guide the selection of appropriate sample preparation and analytical techniques. The high carbon-to-hydrogen ratio imparts good lipophilicity, allowing liquid-liquid extraction with non-polar solvents such as n-hexane or ethyl acetate.
This reference standard is suitable for quantitative analysis on major chromatographic platforms including HPLC, GC, LC-MS/MS, and GC-MS, serving as an external calibration standard or a system suitability test reference material.
CATO manufactures Tris(triphenylphosphine)nickel under ISO 17034:2016 accreditation with dual CNAS and ANAB accreditation. Each batch is characterized by orthogonal methods and supplied with a full Certificate of Analysis (COA), ensuring metrological traceability.
Physical & Chemical Properties
| Molecular Formula | C54H45NiP3 |
| Molecular Weight | 845.55 g/mol |
| Purity | 97%+ |
| Storage | Store at room temperature, protect from light |
| Solubility (reference) | Soluble in chloroform, dichloromethane, ethyl acetate |
| Stability | Light-sensitive; avoid direct strong light |
| Degree of Unsaturation (DBE) | 32.5 |
| UV Absorption | UV-absorbing |
| Structural Features | Aromatic ring present |
| CAS Registry Year (est.) | 1964 |
Related Tris Standards
- 2-[Bis(triphenylphosphine)palladium(II)bromide]benzylalcohol (CAS 849417-41-0)
- Tris(triphenylphosphine)nickel chloride (CAS 15169-64-9)
- Tris(triphenylphosphine)rhodium(1+) (CAS 47897-43-8)
- Tris(triphenylphosphine)palladium (CAS 28516-49-6)
- Bis(triphenylphosphine)palladium(II) bromide (CAS 23523-33-3)
- Bis(triphenylphosphine)platinum dichloride (CAS 10199-34-5)
- Bis(triphenylphosphine)palladium(II) Diacetate (CAS 14588-08-0)
- Triphenylphosphine gold triflimide (CAS 866395-16-6)
Recommended Standards
- 2-Methyl-1,1,3,3,4,4,5,5-octaphenyl-2-(trimethylsilyl)pentasilolane (CAS 56706-07-1)
- Dapagliflozin Impurity 112 (CAS CATO-C4X-1138112)
- 7,10-Bis[O-(triethylsilyl)]-10-deacetyl-13-O-trimethylsilyl Baccatin III (CAS 159383-93-4)
- Dapagliflozin Impurity 192 (CAS CATO-C4X-1138192)
- 1,3-dioxo-1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl methanesulfonate (CAS 1246012-56-5)
- 2',4'-Difluoro-biphenyl-4-ylamine (CAS 445039-99-6)
- 2-(2-Oxo-5-(trifluoromethyl)pyridin-1(2h)-yl)-N-(prop-2-yn-1-yl)acetamide (CAS 923208-24-6)
- 3-Fluoro-5-methoxyphenylacetonitrile (CAS 914637-31-3)
- Ethyl 2-(2-amino-6-chloro-9H-purin-9-yl)acetate (CAS 213552-03-5)
- 1,2,4-Oxadiazole-3-methanamine Hydrochloride (CAS 370103-73-4)
- 1-(5,6-Bis(4-methoxyphenyl)-1,2,4-triazin-3-yl)piperidin-4-ol (CAS 59663-59-1)
- (8-Fluoronaphthalen-1-yl)methanol (CAS 274914-04-4)
- (R)-2-((3-(Trifluoromethyl)phenoxy)methyl)oxirane (CAS 124679-15-8)
- Urotensin II-Related Peptide (human, mouse, rat) (CAS 342878-90-4)
Why CATO?
- ISO 17034 accredited reference material producer (CNAS + ANAB dual accreditation)
- 130,000+ catalog items in stock, COA supplied with every batch
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